2021, 38(5): 30-37.
The composition of aviation kerosene is complicated. In order to construct its chemical reaction dynamic model, this paper constructs and simplifies the combustion mechanism of the main alternative fuel of aviation kerosene, n-dodecane. N-Dodecane is widely used as a single-component surrogate fuel for aviation kerosene, and it is also an important component of multi-component alternative fuel. Through the combination of path flux analysis method and decoupling methodology, the reduced mechanism of n-dodecane with 63 components and 189 reactions was obtained. Under the conditions of temperature 650K-1300K, equivalent ratio 0.5-2.0, and pressure 8-15atm, the ignition delay time, component concentration (CO2, H2O, etc.), laminar flame speed are simulated and compared with experimental data. The results show that the reduced mechanism accurately simulates the flame retardation period of n-dodecane under high pressure, the trend of CO2, H2O and other component concentrations under low equivalence ratio, and the laminar flame speed. This work provides data support for constructing the combustion reaction kinetics model of aviation kerosene multi-component surrogate fuel.