Based on the 65 domestic civil airports and 333 domestic airlines , this paper builds a domestic air cargo network. By collecting the domestic air cargo transport volume in 2016, the author studies air crago network by applying the pajek,and the delivery efficiency of the airline. The results show that the air cargo network has the characteristics of small world, the edge nodes have the priority to connect with the large hub city nodes, the development of network is out-off-balance, and the node capacity of more routes is higher, which leads to the heavy burden of large city nodes, the delivery efficiency of the freight network in our country is low as a whole,in particular the routes connecting the hub nodes and the airline of the southeast coastal areas. The author puts forward the proposal to adjust the structure of air cargo network and increase the efficiency of air freight finally.It is argued that these conclusions can help to analyze the problems existing in current cargo network, and provide the basis for optimizing the structure of freight network and allocation of cargo resources.